Ontology highlight
ABSTRACT:
SUBMITTER: Sarbu LG
PROVIDER: S-EPMC4660956 | biostudies-literature | 2015
REPOSITORIES: biostudies-literature
Sarbu Laura G LG Bahrin Lucian G LG Jones Peter G PG Birsa Lucian M LM Hopf Henning H
Beilstein journal of organic chemistry 20151015
The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite. The 1,3-dithiol-2-thione derivative was in turn synthesized by the regioselective bromination of 4-acetyl[2.2]paracyclophane, then through the corresponding dithiocarbamates and 1,3-dithiolium salts. ...[more]