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?-Stacked Polymer Consisting of a Pseudo?meta?[2.2]Paracyclophane Skeleton.

ABSTRACT: A novel ?-stacked polymer based on a pseudo?meta?linked [2.2]paracyclophane moieties was synthesized by Sonogashira-Hagihara coupling. The UV-vis absorption spectra of the synthesized polymer and model compounds revealed an extension of the conjugation length owing to the through-space conjugation. The optical properties of the ?-stacked dimer with the pseudo?meta?linked [2.2]paracyclophane unit were compared with those of the corresponding dimers with the pseudo?ortho? and pseudo?para?linked [2.2]paracyclophane units.

SUBMITTER: Maeda H 

PROVIDER: S-EPMC6403781 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature

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π-Stacked Polymer Consisting of a Pseudo⁻<i>meta</i>⁻[2.2]Paracyclophane Skeleton.

Maeda Hazuki H   Kameda Mayu M   Hatakeyama Takuji T   Morisaki Yasuhiro Y  

Polymers 20181012 10

A novel π-stacked polymer based on a pseudo⁻<i>meta</i>⁻linked [2.2]paracyclophane moieties was synthesized by Sonogashira-Hagihara coupling. The UV-vis absorption spectra of the synthesized polymer and model compounds revealed an extension of the conjugation length owing to the through-space conjugation. The optical properties of the π-stacked dimer with the pseudo⁻<i>meta</i>⁻linked [2.2]paracyclophane unit were compared with those of the corresponding dimers with the pseudo⁻<i>ortho</i>⁻ and  ...[more]

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