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A Luminescent 1D Silver Polymer Containing [2.2]Paracyclophane Ligands.

ABSTRACT: [2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively.

SUBMITTER: Mackenzie CFR

PROVIDER: S-EPMC8371969 | biostudies-literature |

REPOSITORIES: biostudies-literature

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[2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties.

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