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Thioamination of Alkenes with Hypervalent Iodine Reagents.

ABSTRACT: An efficient thioamination of alkenes mediated by iodine(III) reagents is described. The use of different sulfur nucleophiles allows the flexible synthesis of 1,2-aminothiols from alkenes. By employing chiral iodine(III) reagents, a stereoselective version of the thioamination protocol has also been developed.

SUBMITTER: Mizar P 

PROVIDER: S-EPMC4725223 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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Thioamination of Alkenes with Hypervalent Iodine Reagents.

Mizar Pushpak P   Niebuhr Rebecca R   Hutchings Matthew M   Farooq Umar U   Wirth Thomas T  

Chemistry (Weinheim an der Bergstrasse, Germany) 20160107 5

An efficient thioamination of alkenes mediated by iodine(III) reagents is described. The use of different sulfur nucleophiles allows the flexible synthesis of 1,2-aminothiols from alkenes. By employing chiral iodine(III) reagents, a stereoselective version of the thioamination protocol has also been developed. ...[more]

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