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Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents.

ABSTRACT: A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched ?-arylated ketones without the use of transition metals from readily accessible alkenes.

SUBMITTER: Brown M 

PROVIDER: S-EPMC4797713 | biostudies-literature | 2016 Mar

REPOSITORIES: biostudies-literature

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Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents.

Brown Michael M   Kumar Ravi R   Rehbein Julia J   Wirth Thomas T  

Chemistry (Weinheim an der Bergstrasse, Germany) 20160121 12

A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α-arylated ketones without the use of transition metals from readily accessible alkenes. ...[more]

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