Ontology highlight
ABSTRACT:
SUBMITTER: Janhsen B
PROVIDER: S-EPMC5698881 | biostudies-literature | 2017 Nov
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20170601 22
Radical trifluoromethylation of aryl N,N-dimethyl hydrazones using TBAI as an initiator and Togni's reagent as a trifluoromethyl radical source is described. Cascades proceed via electron-catalysis; this approach is generally more applicable to hydrazone perfluoroalkylation using perfluoroalkyl iodides as the radical precursors in combination with a base under visible-light initiation. ...[more]