Ontology highlight
ABSTRACT:
SUBMITTER: Kou KG
PROVIDER: S-EPMC4847752 | biostudies-literature | 2015 Jul
REPOSITORIES: biostudies-literature
Advanced synthesis & catalysis 20150714 10
The application of the bidentate, electron-rich bisphosphine ligand, 1,3-bis(dicyclohexyl)phosphine-propane (dcpp), in rhodium(I)-catalyzed intermolecular ketone hydroacylation is herein described. Isatins and α-keto amides are shown to undergo hydroacylation with a variety of non-chelating linear and branched aliphatic aldehydes. Also reported is the synthesis of new bidentate chiral phosphine ligands, and their application in hydroacylation is discussed. ...[more]