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Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene.


ABSTRACT: A new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monosubstituted tetraphenylenes. These reactions could accelerate research on the properties and application of tetraphenylene derivatives.

SUBMITTER: Pan S 

PROVIDER: S-EPMC4979733 | biostudies-literature | 2016

REPOSITORIES: biostudies-literature

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Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene.

Pan Shulei S   Jiang Hang H   Zhang Yanghui Y   Zhang Yu Y   Chen Dushen D  

Beilstein journal of organic chemistry 20160622


A new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monosubstituted tetraphenylenes. These reactions could accelerate research on the properties and application of tetraphenylene derivatives. ...[more]

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