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A non-solvated form of [(Z)-O-methyl-N-(2-methyl-phen-yl)-thio-carbamato-?S](tri-phenyl-phosphane-?P)gold(I): crystal structure and Hirshfeld surface analysis.

ABSTRACT: The title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P-Au-S arrangement defined by phosphane P and thiol-ate S atoms with the minor distortion from the ideal [P-Au-S is 177.61?(2)°] being traced in part to the close intra-molecular approach of an O atom [Au?O = 3.040?(2)?Å]. The packing features supra-molecular layers lying parallel to (011) sustained by a combination of C-H?? and ?-? [inter-centroid distance = 3.8033?(17)?Å] inter-actions. The mol-ecular structure and packing are compared with those determined for a previously reported hemi-methanol solvate [Kuan et al. (2008 ?). CrystEngComm, 10, 548-564]. Relatively minor differences are noted in the conformations of the rings in the Au-containing mol-ecules. A Hirshfeld surface analysis confirms the similarity in the packing with the most notable differences relating to the formation of C-H?S contacts between the constituents of the solvate.

SUBMITTER: Yeo CI 

PROVIDER: S-EPMC5050773 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature

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A non-solvated form of [(<i>Z</i>)-<i>O</i>-methyl-<i>N</i>-(2-methyl-phen-yl)-thio-carbamato-κ<i>S</i>](tri-phenyl-phosphane-κ<i>P</i>)gold(I): crystal structure and Hirshfeld surface analysis.

Yeo Chien Ing CI   Tan Sang Loon SL   Tiekink Edward R T ER  

Acta crystallographica. Section E, Crystallographic communications 20160916 Pt 10

The title compound, [Au(C<sub>9</sub>H<sub>10</sub>NOS)(C<sub>18</sub>H<sub>15</sub>P)], features a near linear P-Au-S arrangement defined by phosphane P and thiol-ate S atoms with the minor distortion from the ideal [P-Au-S is 177.61 (2)°] being traced in part to the close intra-molecular approach of an O atom [Au⋯O = 3.040 (2) Å]. The packing features supra-molecular layers lying parallel to (011) sustained by a combination of C-H⋯π and π-π [inter-centroid distance = 3.8033 (17) Å] inter-actio  ...[more]

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