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Crystal structure of chlorido-[1-(4-nitro-phen-yl)thio-urea-?S]bis-(tri-phenyl-phosphane-?P)silver(I).

ABSTRACT: In the title compound, [AgCl(C₇H₇N₃O₂S)(C₁₈H₁₅P)₂], the Ag^I ion is in a distorted tetra-hedral coordination environment formed by P atoms from two tri-phenyl-phosphane ligands, one terminal S atom from the 1-(4-nitro-phen-yl)thio-urea ligand and a chloride ion. In the crystal, bifurcated (N-H)2?Cl hydrogen bonds [with graph-set motif R₂¹(6)] connect complex mol-ecules, forming zigzag chains along [001]. These chains are linked via weak C-H?O hydrogen bonds, forming a two-dimensional network parallel to (100). An intra-molecular N-H?Cl hydrogen bond forming an S(6) ring is also observed.

SUBMITTER: Nimthong-Roldan A

PROVIDER: S-EPMC5458302 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of chlorido-[1-(4-nitro-phen-yl)thio-urea-κS]bis-(tri-phenyl-phosphane-κP)silver(I).

Nimthong-Roldán Arunpatcha A Sripa Paramee P Wattanakanjana Yupa Y

Acta crystallographica. Section E, Crystallographic communications 20170509 Pt 6

In the title compound, [AgCl(C7H7N3O2S)(C18H15P)2], the AgI ion is in a distorted tetra-hedral coordination environment formed by P atoms from two tri-phenyl-phosphane ligands, one terminal S atom from the 1-(4-nitro-phen-yl)thio-urea ligand and a chloride ion. In the crystal, bifurcated (N-H)2⋯Cl hydrogen bonds [with graph-set motif R21(6)] connect complex mol-ecules, forming zig ...[more]

PMID: 28638637

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