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Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation.

ABSTRACT: The synthesis of a new C_3v -symmetric crushed fullerene C₆₀H₂₄ (5) has been accomplished in three steps from truxene through sixfold palladium-catalyzed intramolecular arylation of a syn-trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C₆₀, as detected by LDI-MS.

SUBMITTER: Dorel R

PROVIDER: S-EPMC5053240 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation.

Dorel Ruth R de Mendoza Paula P Calleja Pilar P Pascual Sergio S González-Cantalapiedra Esther E Cabello Noemí N Echavarren Antonio M AM

European journal of organic chemistry 20160502 19

The synthesis of a new C3v -symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium-catalyzed intramolecular arylation of a syn-trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI-MS. ...[more]

PMID: 27774038

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