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Crystal structure of tris[(4,7,13,16,21,24-hexa-oxa-1,10-di-aza-bicyclo-[8.8.8]hexa-cosane-?⁸N₂,O₆)rubidium] rubidium nona-stannide.

ABSTRACT: The crystal structure of the title compound, [Rb(C₁₈H₃₆N₂O₆)]₃RbSn₉, consists of deltahedral [Sn₉]^4- cluster anions, Rb⁺ cations and cryptand mol-ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol-ecules, are neighboured directly to the [Sn₉]^4- clusters and inter-connect them to form _?¹[RbSn₉]^3- chains. These chains extend parallel to [001] and are arranged in a pseudo-hexa-gonal rod packing, separated by the Rb-cryptand complex cations.

SUBMITTER: Klein W

PROVIDER: S-EPMC5290553 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of tris[(4,7,13,16,21,24-hexa-oxa-1,10-di-aza-bicyclo-[8.8.8]hexa-cosane-κ8N2,O6)rubidium] rubidium nona-stannide.

Klein Wilhelm W He Haiyan H Fässler Thomas F TF

Acta crystallographica. Section E, Crystallographic communications 20170113 Pt 2

The crystal structure of the title compound, [Rb(C18H36N2O6)]3RbSn9, consists of deltahedral [Sn9]4- cluster anions, Rb+ cations and cryptand mol-ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol-ecules, are neighboured directly to the [Sn9]4- clusters and inter-connect them to form ∞1[RbSn9 ...[more]

PMID: 28217330

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