Ontology highlight
ABSTRACT:
SUBMITTER: Zhang C
PROVIDER: S-EPMC5395252 | biostudies-literature | 2017 Mar
REPOSITORIES: biostudies-literature
Zhang Chun C Tutkowski Brandon B DeLuca Ryan J RJ Joyce Leo A LA Wiest Olaf O Sigman Matthew S MS
Chemical science 20161209 3
An enantioselective, redox-relay Heck alkenylation of trisubstituted allylic alkenol substrates has been developed. This process enables the construction of vicinal stereocenters in high diastereo- and enantioselectivity and allows the formation of enolizable α-carbonyl methyl-substituted stereocenters with no observed epimerization under the reported reaction conditions. ...[more]