Dataset Information
Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity.
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ABSTRACT:
SUBMITTER: Zhang M
PROVIDER: S-EPMC5609145 | biostudies-literature | 2017 Aug
REPOSITORIES: biostudies-literature
Publications
Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity.
Chemical science 20170619 8
The very rare occurrence of a gas-solid chemical reaction has been found to take place on a molecule within a compact non-porous crystal without destroying its long-range structural order and retaining similar crystal structures when yellow crystals of FeII4(<i>mbm</i>)<sub>4</sub>Cl<sub>4</sub>(MeOH)<sub>4</sub> were exposed to air to give black [FeIII4(<i>mbm</i>)<sub>4</sub>Cl<sub>4</sub>(OH)<sub>4</sub>]·2H<sub>2</sub>O. The latter cannot be synthesised directly. The original cluster underwe ...[more]