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Tunable long persistent luminescence in the second near-infrared window via crystal field control.

ABSTRACT: Construction of an active composite as a biomarker with deeper tissue penetration and higher signal-to-noise ratio (SNR) is of great importance for the application in bioimaging. Here, we report a strategy for tuning the emission bandwidth and intensity via crystal field control in long persistent phosphors (LPPs). Ni²⁺-doped Zn_1+ySn_yGa_2-x-2yO₄ phosphors, with a tunable emission band peaking from 1270 to 1430?nm in the second near-infrared (NIR) window, have been successfully prepared. Such featured materials have the advantages of low absorption and scattering as well as more efficient tissue penetration. The emission spectra can be controlled by tailoring the local crystal field around the activator precisely via substitution of Zn and Sn for Ga. Moreover, with high resolution and weak light disturbance, these developed multi-band afterglow phosphors exhibit great application potential in advanced optical imaging.

SUBMITTER: Nie J

PROVIDER: S-EPMC5622036 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

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Tunable long persistent luminescence in the second near-infrared window via crystal field control.

Nie Jianmin J Li Yang Y Liu Shanshan S Chen Qiuqun Q Xu Qi Q Qiu Jianrong J

Scientific reports 20170929 1

Construction of an active composite as a biomarker with deeper tissue penetration and higher signal-to-noise ratio (SNR) is of great importance for the application in bioimaging. Here, we report a strategy for tuning the emission bandwidth and intensity via crystal field control in long persistent phosphors (LPPs). Ni2+-doped Zn1+ySnyGa2-x-2yO4 phosphors, with a tunable emission band peaking from 1270 to 1430 nm in the second near-infrared ( ...[more]

PMID: 28963563

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