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Bis{?-2,2'-[(3,4-di-thia-hexane-1,6-di-yl)bis-(nitrilo-methanylyl-idene)]bis-(4-bromo-phenolato)-?4O,N,N',O'}dicopper(II).

ABSTRACT: The crystal structure of the title compound, [Cu2(C18H12Br2N4O2S2)2], consists of binuclear complex units which lie across inversion centres and are connected by weak Cu-O coordination bonds forming chains along the b axis. The CuII ion is five-coordinated by two N atoms and two O atoms of the chelating ligand and one symmetry-related O atom forming a square-pyramidal coordination geometry. In the crystal, short S?Br contacts connect neighbouring chains into a two-dimensional network parallel to (101).

SUBMITTER: Rusanova JA 

PROVIDER: S-EPMC5778481 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature

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Bis{μ-2,2'-[(3,4-di-thia-hexane-1,6-di-yl)bis-(nitrilo-methanylyl-idene)]bis-(4-bromo-phenolato)-κ<sup>4</sup><i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'}dicopper(II).

Rusanova Julia A JA   Bederak Dmytro D   Kokozay Vladimir N VN  

Acta crystallographica. Section E, Crystallographic communications 20180101 Pt 1

The crystal structure of the title compound, [Cu<sub>2</sub>(C<sub>18</sub>H<sub>12</sub>Br<sub>2</sub>N<sub>4</sub>O<sub>2</sub>S<sub>2</sub>)<sub>2</sub>], consists of binuclear complex units which lie across inversion centres and are connected by weak Cu-O coordination bonds forming chains along the <i>b</i> axis. The Cu<sup>II</sup> ion is five-coordinated by two N atoms and two O atoms of the chelating ligand and one symmetry-related O atom forming a square-pyramidal coordination geometry.  ...[more]

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