Unknown

Dataset Information

0

Crystal structure of bis(μ-{2-[(5-bromo-2-oxido-benzyl-idene)amino]-eth-yl}sulfanido-κ3 N,O,S){2,2'-[(3,4-di-thia-hexane-1,6-di-yl)bis-(nitrilo-methanylyl-idene)]bis-(4-bromo-phenolato)-κ4 O,N,N',O'}dicobalt(III) di-methyl-formamide monosolvate.

ABSTRACT: The title binuclear CoIII complex, [Co2(C9H8BrNOS)2(C18H16Br2N2O2S2)]·C3H7NO, with a Schiff base ligand formed in situ from cyste-amine (2-amino-ethane-thiol) and 5-bromo-salicyl-aldehyde crystallizes in the space group P21. It was found that during the synthesis the ligand undergoes spontaneous oxidation, forming the new ligand H2 L' having an S-S bond. Thus, the asymmetric unit consists of one Co2(L)2(L') mol-ecule and one DMF solvent mol-ecule. Each CoIII ion has a slightly distorted octa-hedral S2N2O2 coordination geometry. In the crystal, the components are linked into a three-dimensional network by several S⋯ Br, C⋯ Br, C-H⋯Br, short S⋯C (essentially shorter than the sum of the van der Waals radii for the atoms involved) contacts as well by weak C-H⋯O hydrogen bonds. The crystal studied was refined as an inversion twin.

SUBMITTER: Rusanova JA 

PROVIDER: S-EPMC6658961 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of bis(μ-{2-[(5-bromo-2-oxido-benzyl-idene)amino]-eth-yl}sulfanido-κ<sup>3</sup> <i>N</i>,<i>O</i>,<i>S</i>){2,2'-[(3,4-di-thia-hexane-1,6-di-yl)bis-(nitrilo-methanylyl-idene)]bis-(4-bromo-phenolato)-κ<sup>4</sup> <i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'}dicobalt(III) di-methyl-formamide monosolvate.

Rusanova Julia A JA   Kokozay Vladimir N VN   Bondarenko Olena O   Bondarenko Olena O  

Acta crystallographica. Section E, Crystallographic communications 20190524 Pt 6

The title binuclear Co<sup>III</sup> complex, [Co<sub>2</sub>(C<sub>9</sub>H<sub>8</sub>BrNOS)<sub>2</sub>(C<sub>18</sub>H<sub>16</sub>Br<sub>2</sub>N<sub>2</sub>O<sub>2</sub>S<sub>2</sub>)]·C<sub>3</sub>H<sub>7</sub>NO, with a Schiff base ligand formed <i>in situ</i> from cyste-amine (2-amino-ethane-thiol) and 5-bromo-salicyl-aldehyde crystallizes in the space group <i>P</i>2<sub>1</sub>. It was found that during the synthesis the ligand undergoes spontaneous oxidation, forming the new ligand H  ...[more]

Similar Datasets

Unknown Bis{μ-2,2'-[(3,4-di-thia-hexane-1,6-di-yl)bis-(nitrilo-methanylyl-idene)]bis-(4-bromo-phenolato)-κ<sup>4</sup><i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'}dicopper(II).
| S-EPMC5778481 | biostudies-literature
Unknown {4,4',6,6'-Tetra-bromo-2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methanylyl-idene)]diphenolato}copper(II).
| S-EPMC3343805 | biostudies-literature
Unknown 2,2'-[(E,E)-cis-(Cyclo-hexane-1,4-di-yl)bis-(nitrilo-methanylyl-idene)]diphenol.
| S-EPMC3379462 | biostudies-literature
Unknown {5,5'-Bis(diethyl-amino)-2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methanylyl-idene)]diphenolato}dioxido-molybdenum(VI).
| S-EPMC3201348 | biostudies-other
Unknown {4,4'-Dimethyl-2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methanylyl-idene)]diphenolato}nickel(II) monohydrate.
| S-EPMC3254342 | biostudies-literature
Unknown {4,4',6,6'-Tetra-iodo-2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methanylyl-idene)]diphenolato}nickel(II).
| S-EPMC3393197 | biostudies-literature
Unknown Bis(dimethyl-formamide-κO){4,4',6,6'-tetra-chloro-2,2-[butane-1,4-di-yl(nitrilo-methanylyl-idene)]diphenolato-κ(4)O,N,N',O'}nickel(II).
| S-EPMC3393240 | biostudies-literature
Unknown 4,4',6,6'-Tetra-bromo-2,2'-[(E,E)-ethane-1,2-diylbis(nitrilo-methanylyl-idene)]di-phenol.
| S-EPMC3414283 | biostudies-literature
Unknown {2,2'-[(1,2-Di-cyano-ethene-1,2-di-yl)bis-(nitrilo-methanylyl-idyne)]diphenolato-κ(4) O,N,N',O'}(methanol-κO)zinc.
| S-EPMC3772442 | biostudies-literature
Unknown Crystal structure of {6,6'-dibenzoyl-4,4'-di-tert-butyl-2,2'-[(ethane-1,2-di-yl)di-nitrilo-bis-(phenyl-methanylyl-idene)]diphenolato-κ(4) O (1),N,N',O (1')}nickel(II).
| S-EPMC4719819 | biostudies-literature