Porous Aluminum Oxide and Magnesium Oxide Films Using Organic Hydrogels as Structure Matrices.

ABSTRACT: We describe the synthesis of mesoporous Al?O? and MgO layers on silicon wafer substrates by using poly(dimethylacrylamide) hydrogels as porogenic matrices. Hydrogel films are prepared by spreading the polymer through spin-coating, followed by photo-cross-linking and anchoring to the substrate surface. The metal oxides are obtained by swelling the hydrogels in the respective metal nitrate solutions and subsequent thermal conversion. Combustion of the hydrogel results in mesoporous metal oxide layers with thicknesses in the ?m range and high specific surface areas up to 558 m²?g^-1. Materials are characterized by SEM, FIB ablation, EDX, and Kr physisorption porosimetry.

SUBMITTER: Chen Z 

PROVIDER: S-EPMC5923516 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature