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Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl-dithio-carbamato-?2S,S')triphenyl-tin(IV) and [N-methyl-N-(2-phenyl-ethyl)-dithio-carbamato-?2S,S']tri-phenyl-tin(IV).


ABSTRACT: The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamate compounds, viz. [Sn(C6H5)3(C8H16NS2)], (I), and [Sn(C6H5)3(C10H12NS2)], (II), are described. The di-thio-carbamate ligand in each mol-ecule coordinates in an asymmetric fashion resulting in heavily distorted tetra-hedral C3S coordin-ation geometries for the Sn atoms, with the distortions traced to the close approach of the non-coordinating thione-S atom. The mol-ecular packing in both compounds features C-H??(Sn-phen-yl) inter-actions. In (I), the donors are Sn-phenyl-C-H groups leading to centrosymmetric aggregates, while in (II), the donors are both Sn-phenyl-C-H and methyl-C-H groups leading to supra-molecular chains propagating along the b axis. The identified aggregates assemble into their respective crystals with no directional inter-actions between them. An analysis of the Hirshfeld surfaces show distinctive patterns, but an overwhelming predominance (>99% in each case) of H?H, C?H/H?C and S?H/H?S contacts on the respective Hirshfeld surface.

SUBMITTER: Mohamad R 

PROVIDER: S-EPMC5947476 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature

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Crystal structures and Hirshfeld surface analyses of (<i>N</i>-hexyl-<i>N</i>-methyl-dithio-carbamato-κ<sup>2</sup><i>S</i>,<i>S</i>')triphenyl-tin(IV) and [<i>N</i>-methyl-<i>N</i>-(2-phenyl-ethyl)-dithio-carbamato-κ<sup>2</sup><i>S</i>,<i>S</i>']tri-phenyl-tin(IV).

Mohamad Rapidah R   Awang Normah N   Kamaludin Nurul Farahana NF   Jotani Mukesh M MM   Tiekink Edward R T ERT  

Acta crystallographica. Section E, Crystallographic communications 20180406 Pt 5


The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamate compounds, <i>viz</i>. [Sn(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>(C<sub>8</sub>H<sub>16</sub>NS<sub>2</sub>)], (I), and [Sn(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>(C<sub>10</sub>H<sub>12</sub>NS<sub>2</sub>)], (II), are described. The di-thio-carbamate ligand in each mol-ecule coordinates in an asymmetric fashion resulting in heavily distorted tetra-hedral C<sub>3</sub>S coordin-ation geometries for the Sn atoms, with  ...[more]

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