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X-ray structure analysis of symmetrically substituted 1,1'-diformyl-ruthenocene.

ABSTRACT: 1,1'-Di-formyl-ruthenocene, [Ru(C₆H₅O)₂], crystallizes in the ortho-rhom-bic system in the P2₁2₁2₁ space group at room temperature. There are two crystallographically independent mol-ecules in the asymmetric unit. The cyclo-penta-dienyl rings have eclipsed configuration. The mol-ecules self-assemble in a two-dimensional structure by C-H?O and C-H?? inter-actions with cisoid relative orientations of the two formyl groups. The crystal studied was refined as an inversion twin.

SUBMITTER: Anzaldo B

PROVIDER: S-EPMC6127689 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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X-ray structure analysis of symmetrically substituted 1,1'-diformyl-ruthenocene.

Anzaldo Bertin B Sharma Pankaj P Lara Ochoa Francisco F Villamizar C Claudia P CP Gutiérrez Pérez René R

Acta crystallographica. Section E, Crystallographic communications 20180810 Pt 9

1,1'-Di-formyl-ruthenocene, [Ru(C6H5O)2], crystallizes in the ortho-rhom-bic system in the P212121 space group at room temperature. There are two crystallographically independent mol-ecules in the asymmetric unit. The cyclo-penta-dienyl rings have eclipsed configuration. The mol-ecules self-assemble in a two-dimensional structure by C-H⋯O and C-H⋯π inter-actions with cisoid relative orientations of the two formyl gro ...[more]

PMID: 30225096

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