Ontology highlight
ABSTRACT:
SUBMITTER: Huang MH
PROVIDER: S-EPMC6269708 | biostudies-literature | 2013 Jun
REPOSITORIES: biostudies-literature
Huang Mu-Hua MH Li Yi-Xian YX Jia Yue-Mei YM Yu Chu-Yi CY
Molecules (Basel, Switzerland) 20130607 6
Protected L-homoDMDP en-8 and its C-6 epimer en-7 were prepared through two different pathways starting from the vinylpyrrolidine en-9. Based on the NMR and X-ray analysis, the stereochemistry of homoDMDP at C-6 was confirmed to be consistent with reported data. Compounds en-7 and en-8 are general intermediates for the synthesis of a series of 6-C-alkylated DMDP-related natural products, such as broussonetine G, homoDMDP-7-O-apioside, homoDMDP-7-O-b-D-xyloside and so on. ...[more]