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Cu(I)/Ionic Liquids Promote the Conversion of Carbon Dioxide into Oxazolidinones at Room Temperature.

ABSTRACT: Recently, the efficient chemical fixation of carbon dioxide (CO?) into high value chemicals without using noble metal catalysts has become extremely appealing from the viewpoint of sustainable chemistry. In this work, a one-pot three component reaction of propargylic alcohols, anines and CO? that can proceed in an atom economy and environmentally benign manner by combination of CuI and tetrabutylphosphonium imidazol ([P4444][Im]) as a catalyst was described. Catalysis studies indicate that this catalytic system is an effective catalyst for the conversion of CO? into oxazolidinones at room temperature and ambient pressure without any solvent. The results provide a useful way to design novel noble metal-free catalyst systems for the transformation of CO? into other valuable compounds.

SUBMITTER: Qiu J

PROVIDER: S-EPMC6480545 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature

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Cu(I)/Ionic Liquids Promote the Conversion of Carbon Dioxide into Oxazolidinones at Room Temperature.

Qiu Jikuan J Zhao Yue Y Zhao Yuling Y Wang Huiyong H Li Zhiyong Z Wang Jianji J Jiao Tiantian T

Molecules (Basel, Switzerland) 20190329 7

Recently, the efficient chemical fixation of carbon dioxide (CO₂) into high value chemicals without using noble metal catalysts has become extremely appealing from the viewpoint of sustainable chemistry. In this work, a one-pot three component reaction of propargylic alcohols, anines and CO₂ that can proceed in an atom economy and environmentally benign manner by combination of CuI and tetrabutylphosphonium imidazol ([P<sub>4444</sub>][Im]) as a catalyst was described. Catalysis studies indicate ...[more]

PMID: 30934963

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