Ontology highlight
ABSTRACT:
SUBMITTER: Zeng R
PROVIDER: S-EPMC6502446 | biostudies-literature | 2018 Jun
REPOSITORIES: biostudies-literature
Zeng Rong R Feller Moran M Diskin-Posner Yael Y Shimon Linda J W LJW Ben-David Yehoshoa Y Milstein David D
Journal of the American Chemical Society 20180605 23
Both CO and N<sub>2</sub>O are important, environmentally harmful industrial gases. The reaction of CO and N<sub>2</sub>O to produce CO<sub>2</sub> and N<sub>2</sub> has stimulated much research interest aimed at degradation of these two gases in a single step. Herein, we report an efficient CO oxidation by N<sub>2</sub>O catalyzed by a (PNN)Ru-H pincer complex under mild conditions, even with no added base. The reaction is proposed to proceed through a sequence of O-atom transfer (OAT) from N<s ...[more]