Unknown

Dataset Information

0

Crystal structure of N,N'-[(ethane-1,2-di-yl)bis-(aza-nediylcarbono-thio-yl)]bis-(benzamide).

ABSTRACT: The reaction of benzoyl chloride and ethyl-endi-amine in the presence of potassium thio-cyanate yielded a white solid, C18H18N4O2S2, which consists of two benzoyl-thio-ureido moieties connected by an ethyl-ene chain. The asymmetric unit consists of one half of the mol-ecule, the complete mol-ecule being generated by crystallographic inversion symmetry. Both thio-urea moieties are in a trans conformation. An intra-molecular N-H?O hydrogen bond occurs. In the crystal, C-H?S and C-H?O hydrogen bonds link the molecules, forming layers parallel to the ac plane.

SUBMITTER: Samb I 

PROVIDER: S-EPMC6505593 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of <i>N</i>,<i>N</i>'-[(ethane-1,2-di-yl)bis-(aza-nediylcarbono-thio-yl)]bis-(benzamide).

Samb Issa I   Gaye Nango N   Sylla-Gueye Rokhaya R   Thiam Elhadj Ibrahima EI   Gaye Mohamed M   Retailleau Pascal P  

Acta crystallographica. Section E, Crystallographic communications 20190418 Pt 5

The reaction of benzoyl chloride and ethyl-endi-amine in the presence of potassium thio-cyanate yielded a white solid, C<sub>18</sub>H<sub>18</sub>N<sub>4</sub>O<sub>2</sub>S<sub>2</sub>, which consists of two benzoyl-thio-ureido moieties connected by an ethyl-ene chain. The asymmetric unit consists of one half of the mol-ecule, the complete mol-ecule being generated by crystallographic inversion symmetry. Both thio-urea moieties are in a <i>trans</i> conformation. An intra-molecular N-H⋯O hydro  ...[more]

Similar Datasets

Unknown Crystal structure of 4,4'-(ethane-1,2-di-yl)bis-(2,6-di-bromo-aniline).
| S-EPMC4331912 | biostudies-literature
Unknown 1,1'-(Ethane-1,2-di-yl)bis-(3-phenyl-thio-urea).
| S-EPMC3247560 | biostudies-literature
Unknown Crystal structure of bis-[μ-1,2-bis-(di-phenyl-phosphan-yl)ethane-κ(2) P:P']bis[(N,N'-di-ethyl-thio-urea-κS)iodidocopper(I)].
| S-EPMC4555430 | biostudies-literature
Unknown 2,2'-Dihydroxy-N,N'-(ethane-1,2-di-yl)di-benzamide.
| S-EPMC3569262 | biostudies-literature
Unknown Ethane-1,2-diaminium 2,2'-[tereph-thal-oyl-bis(aza-nedi-yl)]di-acetate tetrahydrate.
| S-EPMC4004431 | biostudies-literature
Unknown 1,2-Bis(di-2-pyridylphosphino-yl)ethane.
| S-EPMC2968607 | biostudies-literature
Unknown N,N'-(Ethane-1,2-di-yl)di-benzene-carbo-thio-amide.
| S-EPMC4011219 | biostudies-literature
Unknown 1,1'-(Ethane-1,2-di-yl)bis-(1,4,7-triazonane).
| S-EPMC2979561 | biostudies-literature
Unknown 1,1'-(Ethane-1,2-di-yl)dipyridinium bis-(iodate).
| S-EPMC3151914 | biostudies-literature
Unknown 1,1'-(Ethane-1,2-di-yl)bis-(indoline-2,3-dione).
| S-EPMC3006689 | biostudies-literature