Homo- and Heteropolymetallic Complexes of the Hybrid, Ambidentate N-Heterocyclic Carbene Ligand IMes-acac.

ABSTRACT: The anionic 5-acetylimidazol-2-ylidene-4-olate 1 ^-, named as "IMes-acac", is composed of fused diaminocarbene and acetylacetonato units in the same IMes-based imidazolyl ring. The bifunctional compound 1 ^- is shown to act as an effective, ditopic bridging ligand for transition metal centers. Several new complexes supported by this ligand were prepared, including the complex [RuCl(p-Cym)(κ² O,O-1·H)](BF₄) (2), which can be regarded as a metallated imidazolium salt, the homobimetallic complex [((COD)Rh)(RhCl(COD))(μ-1κ² O,O:2κ¹ C-1)] (4), the heterobimetallic complexes [((p-Cym)ClRu)(RhCl(COD))(μ-1κ² O,O:2κ¹ C-1)] (3), [((p-Cym)ClRu)(RhCl(CO)₂)(μ-1κ² O,O:2κ¹ C-1)] (5), [((p-Cym)ClRu)(Cu(IPr))(μ-1κ² O,O:2κ¹ C-1)] (9), the anionic homoleptic Cu(I) complexes [Cu(κ¹ C-1)₂]K ([10]K) and [Cu(κ¹ C-1)₂](NEt₄) ([10](NEt₄)), and the heterotrimetallic complex [((p-Cym)RuCl)₂(Cu)(μ-1κ² O,O:3κ¹ C-1)(μ-2κ² O,O:3κ¹ C-1)](PF₆) (11). Preliminary studies on the possible preparation of supramolecular metallopolymers and electrochemical studies on the series of complexes are also reported.

SUBMITTER: Cesar V 

PROVIDER: S-EPMC6643943 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature