Characterization of Reactive Organometallic Species via MicroED.
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ABSTRACT:
SUBMITTER: Jones CG
PROVIDER: S-EPMC6764211 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
Publications
Characterization of Reactive Organometallic Species via MicroED.
Jones Christopher G CG Asay Matthew M Kim Lee Joon LJ Kleinsasser Jack F JF Saha Ambarneil A Fulton Tyler J TJ Berkley Kevin R KR Cascio Duilio D Malyutin Andrey G AG Conley Matthew P MP Stoltz Brian M BM Lavallo Vincent V Rodríguez José A JA Nelson Hosea M HM
ACS central science 20190906 9
Here we apply microcrystal electron diffraction (MicroED) to the structural determination of transition-metal complexes. We find that the simultaneous use of 300 keV electrons, very low electron doses, and an ultrasensitive camera allows for the collection of data without cryogenic cooling of the stage. This technique reveals the first crystal structures of the classic zirconocene hydride, colloquially known as "Schwartz's reagent", a novel Pd(II) complex not amenable to solution-state NMR or X- ...[more]
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