Dataset Information
High affinity threading of a new tetralactam macrocycle in water by fluorescent deep-red and near-infrared squaraine dyes.
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ABSTRACT:
SUBMITTER: Dempsey JM
PROVIDER: S-EPMC6827183 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Publications
High affinity threading of a new tetralactam macrocycle in water by fluorescent deep-red and near-infrared squaraine dyes.
Chemical communications (Cambridge, England) 20191008 85
A new tetralactam macrocycle was prepared and found to encapsulate deep-red and near-infrared squaraine and croconaine dyes in water with tunable threading kinetics. The new supramolecular paradigm of guest back-folding was used to increase macrocycle/squaraine affinity by 370-fold and achieve an association constant of 2.8 × 10<sup>9</sup> M<sup>-1</sup>. ...[more]