Ontology highlight
ABSTRACT:
SUBMITTER: Solea AB
PROVIDER: S-EPMC7024227 | biostudies-literature | 2020 Jan
REPOSITORIES: biostudies-literature
Solea Atena B AB Cornu Ivan I Deneva Vera V Crochet Aurelien A Fromm Katharina M KM Antonov Liudmil L Allemann Christophe C Mamula Olimpia O
Molecules (Basel, Switzerland) 20200111 2
Two novel pinene-type ligands have been synthesized and their tautomeric and self-associating behavior studied in solution and in the solid state. The first ligand, an acetylated derivative of 5,6-pinene-bipyridine, displays keto-enol tautomerism in solution. This tautomeric equilibrium was studied by NMR and UV-Vis spectroscopy in various solvents, and the results were compared with the ones obtained through DFT calculations. The second ligand was obtained by an unusual oxidation of the phenant ...[more]