Unknown

Dataset Information

0

Crystal structure of the mixed methanol and ethanol solvate of bis-{3,4,5-trimeth-oxy-N'-[1-(pyridin-2-yl)ethyl-idene]benzohydrazidato}zinc(II).

ABSTRACT: The unit cell of the title compound, [Zn(C17H18N3O4)2]·CH4O·C2H6O, contains two complex mol-ecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimeth-oxy-N'-[1-(pyridin-2-yl)ethyl-idene]benzohydrazide} coordinate to the ZnII ion through the N atoms of the pyridine group and the ketamine, and, additionally, through the O atom of the enolate group. In the crystal, dimers are formed by ?-? inter-actions between the planar ligand moieties, which are further connected by C?O and C?C inter-actions. The inter-molecular inter-actions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most important contributions for the crystal packing are from H?H (44.8%), H?C/C?H (22.2%), H?O/O?H (18.7%) and C?C (3.9%) inter-actions.

SUBMITTER: Znovjyak K 

PROVIDER: S-EPMC7057386 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of the mixed methanol and ethanol solvate of bis-{3,4,5-trimeth-oxy-<i>N</i>'-[1-(pyridin-2-yl)ethyl-idene]benzohydrazidato}zinc(II).

Znovjyak Kateryna K   Fritsky Igor O IO   Sliva Tatiana Y TY   Amirkhanov Vladimir M VM   Seredyuk Maksym M  

Acta crystallographica. Section E, Crystallographic communications 20200206 Pt 3

The unit cell of the title compound, [Zn(C<sub>17</sub>H<sub>18</sub>N<sub>3</sub>O<sub>4</sub>)<sub>2</sub>]·CH<sub>4</sub>O·C<sub>2</sub>H<sub>6</sub>O, contains two complex mol-ecules related by an inversion centre, plus one methanol and one ethanol solvent molecule per complex molecule. In each complex, two deprotonated pyridine aroylhydrazone ligands {3,4,5-trimeth-oxy-<i>N</i>'-[1-(pyridin-2-yl)ethyl-idene]benzohydrazide} coordinate to the Zn<sup>II</sup> ion through the N atoms of the pyr  ...[more]

Similar Datasets

Unknown [(E)-N'-(5-Chloro-2-oxidobenzyl-idene-?O)-3,4,5-trimeth-oxy-benzohydrazidato-?N',O](pyridine-?N)copper(II).
| S-EPMC3089131 | biostudies-literature
Unknown (E)-4-Meth-oxy-N'-(3,4,5-trimeth-oxy-benzyl-idene)benzohydrazide.
| S-EPMC3297292 | biostudies-literature
Unknown 3,4,5-Trimeth-oxy-phenol.
| S-EPMC3515255 | biostudies-literature
Unknown (E)-4-Hy-droxy-N'-(3,4,5-trimeth-oxy-benzyl-idene)benzohydrazide.
| S-EPMC3247387 | biostudies-literature
Unknown N'-(2,4-Dimethoxy-benzyl-idene)-3,4,5-trihydroxy-benzohydrazide ethanol solvate.
| S-EPMC2969598 | biostudies-literature
Unknown N'-(2-Chloro-benzyl-idene)-3,4,5-tri-methoxy-benzohydrazide methanol solvate.
| S-EPMC2962188 | biostudies-literature
Unknown N'-(2-Bromo-benzyl-idene)-3,4,5-tri-methoxy-benzohydrazide methanol solvate.
| S-EPMC2962239 | biostudies-literature
Unknown (E)-N'-[1-(4-Hydroxy-phen-yl)ethyl-idene]-2-(quinolin-8-yl-oxy)acetohydrazide methanol solvate.
| S-EPMC2968527 | biostudies-literature
Unknown (E)-N'-(3,4,5-Trimethoxy-benzyl-idene)-2-(8-quinol-yloxy)acetohydrazide methanol solvate.
| S-EPMC2980132 | biostudies-literature
Unknown {2-Hydr-oxy-N'-[1-(2-oxidophenyl)ethyl-idene]benzohydrazidato}morpholinecopper(II).
| S-EPMC2970954 | biostudies-literature