Ontology highlight
ABSTRACT:
SUBMITTER: Vershinin V
PROVIDER: S-EPMC7467820 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Organic letters 20200212 5
Iron- and manganese-catalyzed <i>para</i>-selective oxidative amination of (4-R)phenols by primary and secondary anilines was developed. Depending on the identity of the R group, the products of this efficient reaction are either benzoquinone anils (C-N coupling) that are produced via a sequential oxidative amination/dehydrogenation (R = H), oxidative amination/elimination (R = OMe) steps, or <i>N</i>,<i>O</i>-biaryl compounds (C-C coupling) that are formed when R = alkyl through an oxidative am ...[more]