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Mechanochemical Palladium-Catalyzed Carbonylative Reactions Using Mo(CO)6.

ABSTRACT: Esters and amides were mechanochemically prepared by palladium-catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real-time monitoring of the mechanochemical reaction by in situ pressure sensing revealed that CO is rapidly transferred from Mo(CO)6 to the active catalytic system without significant release of molecular carbon monoxide.

SUBMITTER: van Bonn P 

PROVIDER: S-EPMC7065133 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Mechanochemical Palladium-Catalyzed Carbonylative Reactions Using Mo(CO)<sub>6</sub>.

van Bonn Pit P   Bolm Carsten C   Hernández José G JG  

Chemistry (Weinheim an der Bergstrasse, Germany) 20200211 12

Esters and amides were mechanochemically prepared by palladium-catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real-time monitoring of the mechanochemical reaction by in situ pressure sensing revealed that CO is rapidly transferred from Mo(CO)<sub>6</sub> to the active catalytic system without significant release of molecular carbon monoxide. ...[more]

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