Ontology highlight
ABSTRACT:
SUBMITTER: Liu Z
PROVIDER: S-EPMC7337986 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20191008 47
We report the development of palladium(0)-catalyzed syn-selective 1,2-carboboration and -silylation reactions of alkenes containing cleavable directing groups. With B<sub>2</sub> pin<sub>2</sub> or PhMe<sub>2</sub> Si-Bpin as nucleophiles and aryl/alkenyl triflates as electrophiles, a broad range of mono-, di-, tri- and tetrasubstituted alkenes are compatible in these transformations. We further describe a directed dearomative 1,2-carboboration of electron-rich heteroarenes by employing this app ...[more]