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Crystal structures of [(N,N-di-methyl-amino)-meth-yl]ferrocene and (R p,R p)-bis-{2-[(di-methyl-amino)-meth-yl]ferrocen-yl}di-methyl-silane.
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ABSTRACT:
SUBMITTER: Krupp A
PROVIDER: S-EPMC7472773 | biostudies-literature | 2020 Sep
REPOSITORIES: biostudies-literature
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Crystal structures of [(<i>N</i>,<i>N</i>-di-methyl-amino)-meth-yl]ferrocene and (<i>R</i> <sub>p</sub>,<i>R</i> <sub>p</sub>)-bis-{2-[(di-methyl-amino)-meth-yl]ferrocen-yl}di-methyl-silane.
Acta crystallographica. Section E, Crystallographic communications 20200811 Pt 9
The title compound [(<i>N</i>,<i>N</i>-di-methyl-amino)-meth-yl]ferrocene, [Fe(C<sub>5</sub>H<sub>5</sub>)(C<sub>8</sub>H<sub>12</sub>N)], (<b>1</b>), is an inter-esting starting material for the synthesis of planar chiral 1,2-disubstituted ferrocenes, as demonstrated by the preparation of (<i>R</i> <sub>p</sub>,<i>R</i> <sub>p</sub>)-bis-{2-[(di-methyl-amino)-meth-yl]ferrocen-yl}di-methyl-silane, [Fe<sub>2</sub>(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>(C<sub>18</sub>H<sub>18</sub>N<sub>2</sub>Si ...[more]