Ontology highlight
ABSTRACT:
SUBMITTER: Ould DMC
PROVIDER: S-EPMC7581293 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Inorganic chemistry 20200901 20
The addition of the Grignard 3,4,5-Ar<sup>F</sup>MgBr to aluminum(III) chloride in ether generates the novel triarylalane Al(3,4,5-Ar<sup>F</sup>)<sub>3</sub>·OEt<sub>2</sub>. Attempts to synthesize this alane via transmetalation from the parent borane with trimethylaluminum gave a dimeric structure with bridging methyl groups, a product of partial transmetalation. On the other hand, the novel alane Al(2,3,4-Ar<sup>F</sup>)<sub>3</sub> was synthesized from the parent borane and trimethylaluminum ...[more]