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Total Synthesis of Cyclopiamide A Using Palladium-Catalyzed Domino Cyclization.

ABSTRACT: Total synthesis of cyclopiamide A was accomplished using a palladium-catalyzed domino cyclization. Three rings in the tetracyclic skeleton of cyclopiamide A were constructed in a one-step domino reaction incorporating double carbopalladation and C-H activation.

SUBMITTER: Park S 

PROVIDER: S-EPMC7660198 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Total Synthesis of Cyclopiamide A Using Palladium-Catalyzed Domino Cyclization.

Park Sunhwa S   Shin Kye Jung KJ   Seo Jae Hong JH  

Molecules (Basel, Switzerland) 20201023 21

Total synthesis of cyclopiamide A was accomplished using a palladium-catalyzed domino cyclization. Three rings in the tetracyclic skeleton of cyclopiamide A were constructed in a one-step domino reaction incorporating double carbopalladation and C-H activation. ...[more]

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