Ontology highlight
ABSTRACT:
SUBMITTER: Li ZF
PROVIDER: S-EPMC2969434 | biostudies-literature | 2009 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090606 Pt 7
The title compound, [Cu(C(12)H(8)N(2))(2)](2)[W(6)O(19)], consists of two [Cu(phen)(2)](+) cations (phen = 1,10-phenanthroline) and one typical [W(6)O(19)](2-) isopolyanion. The Cu(I) atom is coordinated by four N atoms from two bidentate chelating phen ligands in a distorted tetra-hedral geometry. The hexa-tungstate anion, lying on an inversion center and possessing the well known Lindqvist structure, is formed by six edge-sharing WO(6) octa-hedra, thus exhibiting an approximate O(h) symmetry. ...[more]