Dataset Information
Decarboxylative trifluoromethylthiolation of pyridylacetates.
Ontology highlight
ABSTRACT:
SUBMITTER: Kawanishi R
PROVIDER: S-EPMC7849234 | biostudies-literature | 2021
REPOSITORIES: biostudies-literature
Publications
Decarboxylative trifluoromethylthiolation of pyridylacetates.
Beilstein journal of organic chemistry 20210125
Decarboxylative trifluoromethylthiolation of lithium pyridylacetates was achieved using <i>N</i>-(trifluoromethylthio)benzenesulfonimide as the electrophilic trifluoromethylthiolation reagent. The reaction afforded the corresponding trifluoromethyl thioethers in good yield. Furthermore, the preparation of lithium pyridylacetates by saponification of the corresponding methyl esters and subsequent decarboxylative trifluoromethylthiolation were performed in a one-pot fashion. ...[more]