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ABSTRACT:
SUBMITTER: Geringer E
PROVIDER: S-EPMC7898349 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Geringer Eugenie E Gerhard Marina M Koch M M Krug Claudio K CK Gottfried J Michael JM Dehnen Stefanie S
Chemistry (Weinheim an der Bergstrasse, Germany) 20201217 8
Herein, we present the synthesis of two pyrene-functionalized clusters, [(R<sup>pyr</sup> Sn)<sub>4</sub> S<sub>6</sub> ]⋅2 CH<sub>2</sub> Cl<sub>2</sub> (4) and [(R<sup>pyr</sup> Sn)<sub>4</sub> Sn<sub>2</sub> S<sub>10</sub> ]⋅n CH<sub>2</sub> Cl<sub>2</sub> (n=4, 5 a; n=2, 5 b; R<sup>pyr</sup> =CMe<sub>2</sub> CH<sub>2</sub> C(Me)N-NC(H)C<sub>16</sub> H<sub>9</sub> ), both of which form in reactions of the organotin sulfide cluster [(R<sup>N</sup> Sn)<sub>4</sub> S<sub>6</sub> ] (C; R<sup>N</s ...[more]