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Synthesis and crystal structure of catena-poly[[tetra-μ-acetato-copper(II)]-μ-6-eth-oxy-N 2,N 4-bis-[2-(pyridin-2-yl)eth-yl]-1,3,5-triazine-2,4-di-amine].

ABSTRACT: The title compound, [Cu2(C19H23N7O)(C2H3O2)4] n , was obtained via reaction of copper(II) acetate with the coordinating ligand, 6-eth-oxy-N 2,N 4-bis-[2-(pyridin-2-yl)eth-yl]-1,3,5-triazine-2,4-di-amine. The crystallized product adopts the monoclinic P21/c space group. The metal core exhibits a paddle-wheel structure typical for dicopper tetra-acetate units, with triazine and pyridyl nitro-gen atoms from different ligands coordinating to the two axial positions of the paddle wheel in an asymmetric manner. This forms a coordination polymer with the segments of the polymer created by the c-glide of the P21/c setting of the space group. The resulting chains running along the c-axis direction are held together by intra-molecular N-H⋯O hydrogen bonding. These chains are further packed by dispersion forces, producing an extended three-dimensional structure.

SUBMITTER: Ayodele MJ 

PROVIDER: S-EPMC8061112 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

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Synthesis and crystal structure of <i>catena</i>-poly[[tetra-μ-acetato-copper(II)]-μ-6-eth-oxy-<i>N</i> <sup>2</sup>,<i>N</i> <sup>4</sup>-bis-[2-(pyridin-2-yl)eth-yl]-1,3,5-triazine-2,4-di-amine].

Ayodele Mayokun J MJ   Green Travis C TC   Warsapperuma W A Chathuri V WACV   Forbes Malcolm D E MDE   Ostrowski Alexis D AD  

Acta crystallographica. Section E, Crystallographic communications 20210226 Pt 3

The title compound, [Cu<sub>2</sub>(C<sub>19</sub>H<sub>23</sub>N<sub>7</sub>O)(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)<sub>4</sub>] <sub><i>n</i></sub> , was obtained <i>via</i> reaction of copper(II) acetate with the coordinating ligand, 6-eth-oxy-<i>N</i> <sup>2</sup>,<i>N</i> <sup>4</sup>-bis-[2-(pyridin-2-yl)eth-yl]-1,3,5-triazine-2,4-di-amine. The crystallized product adopts the monoclinic <i>P</i>2<sub>1</sub>/<i>c</i> space group. The metal core exhibits a paddle-wheel structure typical  ...[more]

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