Dataset Information

Core-Shell-Like Structured Co₃O₄@SiO₂ Catalyst for Highly Efficient Catalytic Elimination of Ozone.

ABSTRACT: Co₃O₄ is an environmental catalyst that can effectively decompose ozone, but is strongly affected by water vapor. In this study, Co₃O₄@SiO₂ catalysts with a core-shell-like structure were synthesized following the hydrothermal method. At 60% relative humidity and a space velocity of 720,000 h^-1, the prepared Co₃O₄@SiO₂ obtained 95% ozone decomposition for 40 ppm ozone after 6 h, which far outperformed that of the 25wt% Co₃O₄/SiO₂ catalysts. The superiority of Co₃O₄@SiO₂ is ascribed to its core@shell structure, in which Co₃O₄ is wrapped inside the SiO₂ shell structure to avoid air exposure. This research provides important guidance for the high humidity resistance of catalysts for ozone decomposition.

SUBMITTER: Ding J

PROVIDER: S-EPMC8695612 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature

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Core-Shell-Like Structured Co3O4@SiO2 Catalyst for Highly Efficient Catalytic Elimination of Ozone.

Ding Jingya J Cheng Feng F Meng Zhen Z Cao Yan Y Han Fennv F Chen Dongbin D Cao Mingxiang M Zhang Guolin G Kang Jiahao J Xu Shuxiang S Xu Qi Q

Frontiers in chemistry 20211209

Co3O4 is an environmental catalyst that can effectively decompose ozone, but is strongly affected by water vapor. In this study, Co3O4@SiO2 catalysts with a core-shell-like structure were synthesized following the hydrothermal method. At 60% relative humidity and a space velocity of 720,000 h-1, the prepared Co3O4@SiO2 obtained 95% ozone decomposition for 40 ppm ozone after 6 h, which far outperfor ...[more]

PMID: 34957055

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Project description:BackgroundUnderstanding the in vivo size-dependent pharmacokinetics and toxicity of nanoparticles is crucial to determine their successful development. Systematic studies on the size-dependent biological effects of nanoparticles not only help to unravel unknown toxicological mechanism but also contribute to the possible biological applications of nanomaterial.MethodsIn this study, the biodistribution and the size-dependent biological effects of Fe3O4@SiO2-NH2 nanoparticles (Fe@Si-NPs) in three diameters (10, 20 and 40 nm) were investigated by ICP-AES, serum biochemistry analysis and NMR-based metabolomic analysis after intravenous administration in a rat model.ResultsOur findings indicated that biodistribution and biological activities of Fe@Si-NPs demonstrated the obvious size-dependent and tissue-specific effects. Spleen and liver are the target tissues of Fe@Si-NPs, and 20 nm of Fe@Si-NPs showed a possible longer blood circulation time. Quantitative biochemical analysis showed that the alterations of lactate dehydrogenase (LDH) and uric acid (UA) were correlated to some extent with the sizes of Fe@Si-NPs. The untargeted metabolomic analyses of tissue metabolomes (kidney, liver, lung, and spleen) indicated that different sizes of Fe@Si-NPs were involved in the different biochemical mechanisms. LDH, formate, uric acid, and GSH related metabolites were suggested as sensitive indicators for the size-dependent toxic effects of Fe@Si-NPs. The findings from serum biochemical analysis and metabolomic analysis corroborate each other. Thus we proposed a toxicity hypothesis that size-dependent NAD depletion may occur in vivo in response to nanoparticle exposure. To our knowledge, this is the first report that links size-dependent biological effects of nanoparticles with in vivo NAD depletion in rats.ConclusionThe integrated metabolomic approach is an effective tool to understand physiological responses to the size-specific properties of nanoparticles. Our results can provide a direction for the future biological applications of Fe@Si-NPs.

Dataset Information

Core-Shell-Like Structured Co₃O₄@SiO₂ Catalyst for Highly Efficient Catalytic Elimination of Ozone.

Publications

Core-Shell-Like Structured Co<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub> Catalyst for Highly Efficient Catalytic Elimination of Ozone.

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