A weaker donor shows higher oxidation state upon aggregation.
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ABSTRACT:
SUBMITTER: Ma L
PROVIDER: S-EPMC9080441 | biostudies-literature | 2018 May
REPOSITORIES: biostudies-literature
Publications
A weaker donor shows higher oxidation state upon aggregation.
Ma Longfei L Peng Haili H Lu Xiaofeng X Liu Lei L Shao Xiangfeng X
RSC advances 20180511 31
The charge-transfer between TTFs and I<sub>2</sub> shows that the stronger donor TTF1 is in a cation radical state and the weaker donor TTF2 is neutral in solution, whereas TTF1 exists as a cation radical and TTF2 is dicationic in complexes. The dicationic and neutral states of TTF2 are reversible upon aggregation and solvation. ...[more]
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