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Crystal structure and Hirshfeld surface analysis of 2,2'-(phenyl-aza-nedi-yl)bis-(1-phenyl-ethan-1-one).

ABSTRACT: The whole mol-ecule of the title compound, C₂₂H₁₉NO₂, is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, mol-ecules are linked by C-H⋯O contacts with R ² ₂(12) ring motifs, and C-H⋯π inter-actions, resulting in ribbons along the c-axis direction. van der Waals inter-actions between these ribbons consolidate the mol-ecular packing. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from H⋯H (45.5%), C⋯H/H⋯C (38.2%) and O⋯H/H⋯O (16.0%) inter-actions.

SUBMITTER: Naghiyev FN

PROVIDER: S-EPMC9260364 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of 2,2'-(phenyl-aza-nedi-yl)bis-(1-phenyl-ethan-1-one).

Naghiyev Farid N FN Khrustalev Victor N VN Safronenko Marina G MG Akkurt Mehmet M Khalilov Ali N AN Bhattarai Ajaya A Mamedov İbrahim G İG

Acta crystallographica. Section E, Crystallographic communications 20220607 Pt 7

The whole mol-ecule of the title compound, C22H19NO2, is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, mol-ecules are linked by C-H⋯O contacts with R 2 2(12) ring motifs, and C-H⋯π inter-actions, resulting in ribbons along the c-axis direction. van der Waals inter-actions between these ribbons consolidate the mol-ecular packi ...[more]

PMID: 35855356

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