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Bis(isonicotinamide-κN)silver(I) tri-fluoro-methane-sulfonate aceto-nitrile disolvate.

ABSTRACT: The central Ag^I atom of the title salt, [Ag(INAM)₂](CF₃SO₃)·2CH₃CN, where INAM is isonicotinamide (C₆H₆N₂O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol-ecular geometry. The formation of polymeric chains {[Ag(INAM)₂]⁺} _n , held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating aceto-nitrile mol-ecules that inter-act the silver metal center via regium bonds.

SUBMITTER: Adrian RA

PROVIDER: S-EPMC9462304 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature

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Bis(isonicotinamide-κN)silver(I) tri-fluoro-methane-sulfonate aceto-nitrile disolvate.

Adrian Rafael A RA Ibarra Sara J SJ Arman Hadi D HD

IUCrData 20211021 Pt 10

The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol-ecular geometry. The formation of polymeric chains {[Ag(INAM)2]+} n , held together by discrete hydrogen bonds through the amide group of the IN ...[more]

PMID: 36340985

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