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Crystal structure of tri-chlorido-(4'-ferrocenyl-2,2':6',2''-terpyridine-?(3) N,N',N'')iridium(III) aceto-nitrile disolvate.

ABSTRACT: In the title compound, [FeIr(C5H5)(C20H14N3)Cl3]·2CH3CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa-hedral fashion. The terpyridine ligand is functionalized at the 4'-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, mol-ecules are stacked in rows parallel to [001], with the aceto-nitrile solvent mol-ecules situated between the rows. An extensive network of intra- and inter-molecular C-H?Cl inter-actions is present, stabilizing the three-dimensional structure.

SUBMITTER: Davaasuren B

PROVIDER: S-EPMC4350693 | biostudies-literature | 2015 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of tri-chlorido-(4'-ferrocenyl-2,2':6',2''-terpyridine-κ(3) N,N',N'')iridium(III) aceto-nitrile disolvate.

Davaasuren Bambar B Padhy Harihara H Rothenberger Alexander A

Acta crystallographica. Section E, Crystallographic communications 20150225 Pt 3

In the title compound, [FeIr(C5H5)(C20H14N3)Cl3]·2CH3CN, the central Ir(III) atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa-hedral fashion. The terpyridine ligand is functionalized at the 4'-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, mol-ecules are stacked in rows parallel to [001], with the aceto-nitrile solvent mol-ecules situated between the rows. An extensive network of intr ...[more]

PMID: 25844213

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