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Di-chlorido-(η⁶-p-cymene)[tris-(4-meth-oxy-phen-yl)phosphane]ruthenium(II).

ABSTRACT: The title compound, [RuCl₂(C₁₀H₁₄)(C₂₁H₂₁O₃P)], crystallizes with two complex mol-ecules in the asymmetric unit. The Ru^II atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru-centroid = 1.707 (2)/1.704 (2) Å], a tris-(4-meth-oxy-phen-yl)phosphane ligand [Ru-P = 2.3629 (15)/2.3665 (15) Å] and two chloride atoms with the Ru-Cl bonds adopting two distinct values of 2.4068 (16)/2.4167 (16) and 2.4016 (15)/2.4244 (16) Å. The effective cone and solid angles for the phosphane ligands were calculated to be 149.5/150.2° and 25.3/25.6°, respectively. In the crystal, weak C-H⋯Cl/O/π inter-actions are observed. The crystal was refined as a two-component twin.

SUBMITTER: Davis WL

PROVIDER: S-EPMC9462307 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

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Di-chlorido-(η6-p-cymene)[tris-(4-meth-oxy-phen-yl)phosphane]ruthenium(II).

Davis Wade L WL Muller Alfred A

IUCrData 20211202 Pt 12

The title compound, [RuCl2(C10H14)(C21H21O3P)], crystallizes with two complex mol-ecules in the asymmetric unit. The RuII atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru-centroid = 1.707 (2)/1.704 (2) Å], a tris-(4-meth-oxy-phen-yl)phosphane ligand [Ru-P = 2.3629 (15)/2.3665 (15) Å] and two chloride atoms with the Ru-Cl bonds adopting two distinct values of 2.4068 (16)/ ...[more]

PMID: 36337593

Similar Datasets

Dichlorido(?(6)-p-cymene)(eth-oxy-diphenyl-phosphane)ruthenium(II).

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Synthesis, crystal structure and catalytic activity in reductive amination of di-chlorido-(η6-p-cymene)(2'-di-cyclo-hexyl-phosphanyl-2,6-di-meth-oxy-biphen-yl-κP)ruthenium(II).

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Crystal structure of [3-amino-2-(phenyl-diazenyl)-pyridine]chlorido-(η(6)-p-cymene)-ruthenium(II) chloride.

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trans-Dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate.

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trans-Carbonyl-chloridobis[tris-(4-meth-oxy-phen-yl)phosphane-?P]rhodium(I).

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trans-Dichloridobis[tris-(4-meth-oxy-lphen-yl)phosphane-?P]platinum(II) acetone disolvate.

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catena-Poly[[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolato}-cad-mium(II)]-di-μ(2)-chlorido-[dimethanol-cadmium(II)]-di-μ(2)-chlorido-[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]-phenolato}cadmium(II)]-di-μ(2)-chlorido].

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