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Crystal structure of [3-amino-2-(phenyl-diazenyl)-pyridine]chlorido-(?(6)-p-cymene)-ruthenium(II) chloride.

ABSTRACT: The title compound, [RuCl(C10H14)(C11H10N4)]Cl is an Ru(II) complex in which an ? (6) -p-cymene ligand, two N atoms of 3-amino-2-(phenyl-azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N-H?Cl hydrogen bonds play an important role in the formation of the supramolecular zigzag chain along the a-axis direction. Disorder is observed for the isopropyl group with site-occupancy factors refined to 0.78?(5) and 0.22?(5).

SUBMITTER: Hansongnern K

PROVIDER: S-EPMC4647410 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of [3-amino-2-(phenyl-diazenyl)-pyridine]chlorido-(η(6)-p-cymene)-ruthenium(II) chloride.

Hansongnern Kanidtha K Sansook Supojjanee S Romin Thassani T Nimthong Roldan Arunpatcha A Pakawatchai Chaveng C

Acta crystallographica. Section E, Crystallographic communications 20150926 Pt 10

The title compound, [RuCl(C10H14)(C11H10N4)]Cl is an Ru(II) complex in which an η (6) -p-cymene ligand, two N atoms of 3-amino-2-(phenyl-azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N-H⋯Cl hydrogen bonds play an important role in the formation of the supramolecular zigzag chain along the a-axis direction. Disorder is observed for the isopropyl group with site-occupancy factors refined to 0.78 (5) and 0.22 (5). ...[more]

PMID: 26594428

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