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Chlorido(chloro-diphenyl-phosphine-?P)(diphenyl-piperidinophosphine-?P)(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II).

ABSTRACT: The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chloro-diphenyl-phosphine ligand formed from the diphenyl-piperidinophosphine and chlorine of the precursor complex [Ru(?(5)-C(5)Me(5))(?(1)P-Ph(2)PNC(5)H(10))Cl(2)] by an unexpected reaction with NaBH(4). The complex has a three-legged piano-stool geometry, with Ru-P bond lengths of 2.2598?(5)?Å for the chloro-phosphine and 2.3303?(5)?Å for the amino-phosphine.

SUBMITTER: Jantscher F

PROVIDER: S-EPMC2977503 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Chlorido(chloro-diphenyl-phosphine-κP)(diphenyl-piperidinophosphine-κP)(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II).

Jantscher Florian F Kirchner Karl K Mereiter Kurt K

Acta crystallographica. Section E, Structure reports online 20090718 Pt 8

The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chloro-diphenyl-phosphine ligand formed from the diphenyl-piperidinophosphine and chlorine of the precursor complex [Ru(η(5)-C(5)Me(5))(κ(1)P-Ph(2)PNC(5)H(10))Cl(2)] by an unexpected reaction with NaBH(4). The complex has a three-legged piano-stool geometry, with Ru-P bond lengths of 2.2598 (5) Å for the chloro-phosphine and 2.3303 (5) Å for the amino-phosphine. ...[more]

PMID: 21583392

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