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Octa-deca-bromidobis(dicarbido)deca-dysprosium, [Dy(10)Br(18)(C(2))(2)].

ABSTRACT: Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa-hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by Br atoms above the cluster edges and vertices, respectively. The dimers are connected to each other by Br atoms, leading to a three-dimensional network. [Dy(10)Br(18)(C(2))(2)] is isotypic with its iodido analogue [Dy(10)I(18)(C(2))(2)].

SUBMITTER: Daub K

PROVIDER: S-EPMC2914882 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Octa-deca-bromidobis(dicarbido)deca-dysprosium, [Dy(10)Br(18)(C(2))(2)].

Daub Kathrin K Meyer Gerd G

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa-hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by Br atoms above the cluster edges and vertices, respectively. The dimers are connected to each other by Br atoms, leading to a three-dimensional network. [Dy(10)Br(18)(C(2))(2)] is isotypic with its io ...[more]

PMID: 21200454

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