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Bis[bis-(1H-benzimidazol-2-ylmeth-yl)amine]copper(II) dichloride methanol disolvate dihydrate.

ABSTRACT: In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis-(1H-benzimidazol-2-ylmeth-yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa-hedral with an N(6) ligand set. A three-dimensional framework structure is formed by means of hydrogen bonds and ?-? inter-actions formed between imidazole and phenyl rings, and between phenyl and phenyl rings, with centroid-to-centroid distances of 3.690?(2)-3.977?(2)?Å and interplanar spacings of 3.445?(2)-3.502?(2)?Å.

SUBMITTER: Xia XY 

PROVIDER: S-EPMC2915122 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Bis[bis-(1H-benzimidazol-2-ylmeth-yl)amine]copper(II) dichloride methanol disolvate dihydrate.

Xia Xian-You XY   Zhang Yong Y   Qu Yuan Y   Chen Xue-Mei XM   Liu Ting T  

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis-(1H-benzimidazol-2-ylmeth-yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa-hedral with an N(6) ligand set. A three-dimensional framework structure is formed by means of hydrogen bonds and π-π inter-actions formed between imidazole and phenyl rings, and between phenyl and phenyl rings, with  ...[more]

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