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Chlorido{5-chloro-2-[2-(methyl-sulfanyl)phenyl-diazen-yl]phenyl}-platinum(II).

ABSTRACT: The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra-coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol-ecules dimerize through a nonbonded S?S inter-action [S?S = 3.523?(18)?Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter-molecular ?-? inter-actions; the centroid-centroid distances are 3.804?(3), 3.638?(3), 3.804?(3) and 3.638?(3)?Å, and the corresponding perpendicular distances are 3.369, 3.448, 3.406 and 3.466?Å.

SUBMITTER: Bagchi V

PROVIDER: S-EPMC2960293 | biostudies-other | 2008 Jan

REPOSITORIES: biostudies-other

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Chlorido{5-chloro-2-[2-(methyl-sulfanyl)phenyl-diazen-yl]phenyl}-platinum(II).

Bagchi Vivek V Bandyopadhyay Debkumar D

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra-coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol-ecules dimerize through a nonbonded S⋯S inter-action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter-molecular π-π inter-actions; the centroid-centroid distances are 3.804 (3), 3.638 (3), 3.804 (3) and 3.638 (3) Å, and the corresponding perpendicular distances a ...[more]

PMID: 21201318

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